Syntheses of Penta-O-benzyl-myo-inositols, O-β-L-Arabinosyl-(1 → 2)-sn-myo-inositol, O-α-D-Galactosyl-(1 → 3)-sn-myo-inositol, and O-α-D-Galactosyl-(1 → 6)-O-α-D-galactosyl-(1 → 3)-sn-myo-inositol

Autor: Koto, Shinkiti, Hirooka, Motoko, Yoshida, Toyosaku, Takenaka, Kazuhiro, Asai, Chizuru, Nagamitsu, Toshiki, Sakuma, Hiroaki, Sakurai, Michiyo, Masuzawa, Shinichi, Komiya, Mitsuo, Sato, Tadaaki, Zen, Shonosuke, Yago, Kazuo, Tomonaga, Fumiya
Zdroj: Bulletin of the Chemical Society of Japan; November 2000, Vol. 73 Issue: 11 p2521-2529, 9p
Abstrakt: Two-step conversions of myo-inositol into (±)-2,3,4,5,6- and 1,3,4,5,6-penta-O-benzyl-myo-inositols are described. Starting from these monohydroxy derivatives of myo-inositol, O-β-L-arabinopyranosyl-(1 → 2)-sn-myo-inositol from Japanese green tea [SENCHA], Camellia sinensis, and O-α-D-galactopyranosyl-(1 → 3)-sn-myo-inositol (galactinol) as well as its homolog, O-α-D-galactopyranosyl-(1 → 6II)-galactinol, were synthesized by way of the in situ activating glycosylation procedure.
Databáze: Supplemental Index