ortho-Disubstituted F-Benzenes. II. One-pot Syntheses of (F-Benzo)heterocyclic Compounds
| Autor: | Inukai, Yoshinari, Sonoda, Takaaki, Kobayashi, Hiroshi |
|---|---|
| Zdroj: | Bulletin of the Chemical Society of Japan; September 1979, Vol. 52 Issue: 9 p2657-2660, 4p |
| Abstrakt: | Convenient one-pot methods of converting F-benzene into substituted (F-benzo)furans, (F-benz)oxazole, -imidazolines, and -thiazoline are described. Ambident nucleophiles are generated in situfrom ketone, amide, urea, thiourea, and their derivatives in the presence of sodium hydride. Enolate-anion nucleophiles are also generated in situfrom silyl enol ethers in the presence of potassium fluoride in anhydrous DMF. |
| Databáze: | Supplemental Index |
| Externí odkaz: |
|