Generation of Nitrile Oxides from Oxime Derivatives by the Oxidation with Ammonium Hexanitratocerate(IV)

Autor: Arai, Noriyoshi, Iwakoshi, Mitsuhiko, Tanabe, Katsuhiko, Narasaka, Koichi
Zdroj: Bulletin of the Chemical Society of Japan; October 1999, Vol. 72 Issue: 10 p2277-2285, 9p
Abstrakt: Aromatic and aliphatic nitrile oxides are generated by the oxidation of α-hydroxyimino carboxylic acid with ammonium hexanitratocerate(IV). They react with olefinic and acetylenic dipolarophiles to give the corresponding cycloaddition products in good yield. The oxidation of α-oxo aldoximes also affords α-oxo carbonitrile oxides.
Databáze: Supplemental Index