New Series of Organic Metal. Radical Salts of Unsymmetrical Donors Containing Pyrazino Group

Autor: Kikuchi, Koichi, Kamio, Hiroyuki, Saito, Kazuya, Yiannopoulos, Stelios Y, Papavassiliou, George C, Kobayashi, Keiji, Ikemoto, Isao
Zdroj: Bulletin of the Chemical Society of Japan; March 1988, Vol. 61 Issue: 3 p741-743, 3p
Abstrakt: The I3, ClO4, and PF6salts of unsymmetrical donors containing fused pyrazino groups (DMPDSDTF and DM(DMP)DSDTF) were prepared electrochemically and their electrical conductivities were measured. The I3salt of DM(DMP)DSDTF exhibited a metallic behavior down to about 120 K. The radical salts of unsymmetrical donors showed much larger conductivities than those of the corresponding symmetrical donors containing pyrazino groups.
Databáze: Supplemental Index