| Autor: |
Jing, Shu-Xi, Fu, Ran, Li, Chun-Huan, Hugelshofer, Cedric L., Shi, Yi-Ming, Luo, Shi-Hong, Liu, Yan-Chun, Liu, Yan, Li, Sheng-Hong |
| Zdroj: |
Journal of Natural Products; November 2023, Vol. 86 Issue: 11 p2468-2473, 6p |
| Abstrakt: |
Three unusual sesterterpenoids featuring unprecedented rearranged colquhounane (C25) and tetranorcolquhounane (C21) frameworks, colquhounoids E (1) and F (3) and norcolquhounoid F (2), were isolated from a Lamiaceae medicinal plant Colquhounia coccineavar. mollis. Their structures were elucidated by spectroscopic analysis and quantum chemical calculations. A biomimetic inspired regioselective cyclopropane cleavage was achieved under acidic conditions. The immunosuppressive activities of these new sesterterpenoids were also evaluated. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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