| Autor: |
Ramaswamy, Nagappan, Zulevi, Barr, McCool, Geoff, Shi, Zixiao, Chavez, Aldo, Muller, David A., Kongkanand, Anusorn, Kumaraguru, Swami |
| Zdroj: |
ACS Applied EngineeringMaterials; October 2023, Vol. 1 Issue: 10 p2543-2554, 12p |
| Abstrakt: |
As proton exchange membrane fuel cells mature into commercial devices capable of powering a wide range of stationary and automotive applications, they need materials with tunable properties to improve their performance and durability. Carbon supports used for platinum (Pt) nanoparticle dispersion is typically based on a furnace black-type material with a random structure, thereby hindering progress in catalyst development. To address this challenge, engineered carbons with a tunable mesoporous structure offer an opportunity to maximize catalyst performance and durability. In this article, we report on the development of a graphitized, mesoporous carbon support with a high degree of ordering, labeled here as ECS4005, for the dispersion of Pt nanoparticles. Pt/ECS4005 shows significantly improved kinetic activity due to its mesoporous structure that mitigates Pt poisoning by sulfonate functional groups in the ionomer while simultaneously enabling favorable accessibility to reactants. |
| Databáze: |
Supplemental Index |
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