| Autor: |
Qiu, Jiang-Zhen, Guo, Cheng-Jie, Wu, Qinwu, Liao, Pei-Yu, Deng, Jinyu, Chen, Zhuo-Fan, Yao, Suyang, Lin, Wei-Quan, Jiang, Jiuxing |
| Zdroj: |
Inorganic Chemistry; 20230101, Issue: Preprints |
| Abstrakt: |
Designing and innovating organic structure-directing agents is the key to synthesizing novel molecular sieve structures. Herein, we design a novel carbazolyl-modified template and further synthesize a two-dimensional layered aluminophosphate with [C17H21N2]3[Al3(PO4)4]·5H2O (denoted as ZHKU-2). ZHKU-2 is composed of AA-stacked [Al3P4O16]3–layers constructed from alternating AlO4and PO3(=O) tetrahedrons to form a 4.6.8 network featured by capped six-ring secondary building units. Carbazolyl-templated ZHKU-2 exhibits strong purple fluorescence with a high quantum yield of 25.98%. This work expands aluminophosphate materials of the [Al3P4O16]3–family and provides a view for synthesizing new molecular sieves by exploring the organic luminescence structure–directing agents. |
| Databáze: |
Supplemental Index |
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