| Autor: |
Bai, Yuyang, Cao, Liping, Li, Siyuan, Zhang, Guang’an, Liu, Yingguo, Zhao, Fengqian, Wu, Junliang |
| Zdroj: |
Organic Letters; 20230101, Issue: Preprints |
| Abstrakt: |
A photoredox/Lewis acid cooperative catalytic system has been developed for the construction of Cvinyl–CRfbonds through the dehydrative difluoroalkylation of benzyl alcohols. A variety of allylic gem-difluorides could be obtained in moderate yields with good to excellent E/Zselectivity. In addition, several control experiments have been explored, and a possible mechanism was proposed for this process. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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