Antiferromagnetic to Ferrimagnetic Phase Transition and Possible Phase Coexistence in Polar Magnets (Fe1–xMnx)2Mo3O8(0 ≤ x≤ 1)

Autor: Chang, Yuting, Gao, Lei, Xie, Yunlong, You, Bin, Liu, Yong, Xiong, Rui, Wang, Junfeng, Lu, Chengliang, Liu, Jun-Ming
Zdroj: ACS Applied Materials & Interfaces; May 2023, Vol. 15 Issue: 18 p22204-22211, 8p
Abstrakt: In the present work, the magnetic properties of a single crystal (Fe1–xMnx)2Mo3O8(0 ≤ x≤ 1) have been studied by performing extensive measurements. A detailed magnetic phase diagram is built up, in which the antiferromagnetic state dominates for x≤ 0.25 and the ferrimagnetic phase arises for x≥ 0.3. Meanwhile, a sizeable electric polarization of spin origin is commonly observed in all samples, no matter what the magnetic state is. For the samples hosting a ferrimagnetic state, square-like magnetic hysteresis loops are revealed, while the remnant magnetization and coercive field can be tuned drastically by simply varying the Mn content or temperature. A possible coexistence of the antiferromagnetic and ferrimagnetic phases is proposed to be responsible for the remarkable modulation of magnetic properties in the samples.
Databáze: Supplemental Index