Reactions of co-ordinated ligands: Kinetics and mechanisms in the charge transfer interaction between dichloro or diaquo triethylene tetramine Co(III) and ferrocyanide

Autor:	Visalakshi, G., Venkateswarlu, K. S.
Zdroj:	Proceedings Mathematical Sciences; June 1982, Vol. 91 Issue: 3 p213-221, 9p
Abstrakt:	The cherry red-coloured solid state product obtained by the reaction ofcis-σdiaquo Co (III) triethylene tetramine with ferrocyanide was examined by thermogravimetric, infrared and Mössbauer techniques. Its electronic spectrum in aqueous medium was interpreted to consist of charge transfer IT transition at 440 nm and a ligand field transition around 330 nm. The kinetics of formation of this 1:1 product in solution was also studied.
Databáze:	Supplemental Index
Externí odkaz:	Zobrazit plný text záznamu Full text from SpringerLink