| Autor: |
Anderson, L. L., Arnold, J., Bergman, R. G. |
| Zdroj: |
Organic Letters; July 2004, Vol. 6 Issue: 15 p2519-2522, 4p |
| Abstrakt: |
Several tantalum imido complexes have been synthesized and shown to efficiently catalyze the hydroamination of internal and terminal alkynes. An unusual hydroamination/hydroarylation reaction of norbornene catalyzed by a highly electrophilic cationic tantalum imido complex is also reported. Factors affecting catalyst activity and selectivity are discussed along with mechanistic insights gained from stoichiometric reactions. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
