| Autor: |
Kovalev, I S, Kopchuk, D S, Zyryanov, G V, Rusinov, V L, Chupakhin, O N, Charushin, V N |
| Zdroj: |
Russian Chemical Reviews; December 2015, Vol. 84 Issue: 12 |
| Abstrakt: |
The review considers the most typical examples of the direct non-activated non-catalytic C–C bond formation in arenes and their metal complexes activated by electron-withdrawing substituents in the aromatic nucleus and in hetarenes (azines and their N-oxides, porphyrins, etc.) upon the reactions with aliphatic and (hetero)aromatic (hetero)organolithium nucleophiles. Particular attention is given to the direct introduction of nitroxide radicals and (hetero)organic moieties into mono-, di- and triazines and their N-oxides. The influence of the structures of the (hetero)aromatic substrate and the (hetero)organolithium nucleophile on the reaction pathway and rate and on the structure of the reaction product is analyzed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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