| Autor: |
Mankad, N. P., Laitar, D. S., Sadighi, J. P. |
| Zdroj: |
Organometallics; July 2004, Vol. 23 Issue: 14 p3369-3371, 3p |
| Abstrakt: |
The monomeric, two-coordinate carbene complex (IPr)CuO-t-Bu (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) reacts readily with silanes such as triethoxysilane, forming a dimeric copper(I) hydride complex (2) with a very short copper−copper distance. Hydrocupration of 3-hexyne by 2 affords a monomeric copper(I) vinyl complex. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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