| Autor: |
Gong, Huihua, Cui, Tianhua, Liu, Zheyuan, Zheng, Yanling, Zheng, Xueli, Fu, Haiyan, Yuan, Maolin, Chen, Hua, Xu, Jiaqi, Li, Ruixiang |
| Zdroj: |
Catalysis Science & Technology; 2022, Vol. 12 Issue: 20 p6213-6218, 6p |
| Abstrakt: |
Three novel Ru(ii)–CNN complexes, namely, [RuH(CO)(PPh3)2(κ2-NimN)]Cl2(1), [fac-RuH(CO)(PPh3)(κ3-CNHN)]Cl (2) and [fac-RuH(CO)(PPh3)(κ3-CNMeN)]Cl (3), have been synthesized for efficient CO2hydrogenation to formate. Complex 2bearing a CNHN ligand exhibits excellent activity and a long catalytic lifetime of 400 h at 170 °C. Notably, the addition of PPh3leads to increased activity and gives a high TON of 6.5 × 105after 400 h. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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