| Autor: |
Sieger, Monika, Sarkar, Biprajit, Záliš, Stanislav, Fiedler, Jan, Escola, Natalia, Doctorovich, Fabio, Olabe, José A., Kaim, Wolfgang |
| Zdroj: |
Dalton Transactions; 2004, Vol. 2004 Issue: 12 |
| Abstrakt: |
Predominantly NO-centered reduction was observed by EPR and IR spectroelectrochemistry to occur reversibly at low temperatures for [Cl5Ir(NO)]−. In contrast, the [Cl5Ru(NO)]2− ion was found to undergo only irreversible reduction but reversible oxidation to a ruthenium(iii) species at −40°C. DFT calculations were used to establish the electronic structures and to rationalise the different stabilities. The calculations also reveal orientation-dependent energies and EPR properties between staggered and eclipsed conformations. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
