| Autor: |
Mando, Morgane, Fares, Mathieu, Kowandy, Christelle, Grellepois, Fabienne, Riguet, Emmanuel |
| Zdroj: |
Organic Letters; July 2022, Vol. 24 Issue: 29 p5351-5355, 5p |
| Abstrakt: |
The synthesis of enantioenriched α-aryl-α′-allyl-γ-butyrolactones bearing vicinal tertiary and quaternary stereocenters through organocatalyzed asymmetric allylic alkylation is reported. The process demonstrated that weakly stabilized enolates derived from α-aryl-γ-butyrolactones can undergo regio-, diastereo-, and enantioselective allylation using the proper activation of Morita–Baylis–Hillman (MBH) carbonates. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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