Autor: |
Serafin, S. V., Zhang, K., Aurelio, L., Hughes, A. B., Morton, T. H. |
Zdroj: |
Organic Letters; May 2004, Vol. 6 Issue: 10 p1561-1564, 4p |
Abstrakt: |
Protonated threonine and its allo diastereomer exhibit different proportions of collisionally activated dissociation (CAD) product ions. N-Methylation attenuates these differences. Water loss from protonated allo-threonine gives protonated trans-3-methylaziridinecarboxylic acid via an internal SN2 pathway, rather than protonated vinylglycine. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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