| Autor: |
Golczewski, Jerzy A., Aldinger, Fritz |
| Zdroj: |
International Journal of Materials Research: Zeitschrift fuer Metallkunde; January 2022, Vol. 97 Issue: 2 p114-118, 5p |
| Abstrakt: |
Details of phase separation in the microstructure of amorphous Si – (B) –C–N ceramics derived from polymers have been resolved using the recent results of structural investigations. The formation of an amorphous phase built of atomic compounds SiCi/4N(4 – i)/3and consequently located along the composition line between SiC and Si3N4in the ternary Si–C–N phase diagram demonstrates a generic feature of phase separation in all these materials. The amorphous carbon phase separates as a counterpart in the micro-structure of Si –C–N ceramics, and in the case of Si –B– C–N ceramics such counterpart represents B–N–C domains of the composition (BN)cCylocated along the tie line C–BN in the ternary B–C–N phase diagram. The effect of phase separation has been also pondered as a source of exceptional material properties. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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