| Autor: |
White, R. D., Keaney, G. F., Slown, C. D., Wood, J. L. |
| Zdroj: |
Organic Letters; April 2004, Vol. 6 Issue: 7 p1123-1126, 4p |
| Abstrakt: |
The total synthesis of kalihinol C, a bis-isonitrile marine diterpenoid isolated from Acanthella sp., is reported. The decalin framework was established via an intramolecular Diels−Alder cycloaddition and subsequently functionalized through a series of substrate-controlled diastereoselective transformations to install the tertiary isonitrile, β-hydroxy isonitrile, and pendant tetrahydrofuranyl ring. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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