A novel and efficient synthesis of 5-substituted and 5,6-disubstituted 4-methylcoumarins using organocerium(III) reagents

Autor: Nagasawa, Kazuo, Kanbara, Hajime, Matsushita, Kazuya, Ito, Keiichi
Zdroj: Tetrahedron Letters; January 1985, Vol. 26 Issue: 52 p6477-6480, 4p
Abstrakt: Addition of organocerium(III) reagent, Cl2CeCH2COOt-Bu, to the appropriate ortho-methoxymethoxyacetophenones followed by acid-treatment gives 5-substituted and 5,6-disubstituted 4-methylcoumarins in excellent yields.
Databáze: Supplemental Index