Enantioselectivity of the PPL-catalysed hydrolysis of racemic esters: some cases implying a conformational substrate model

Autor:	Serebryakov, Edward P., Gamalevich, Galina D.
Zdroj:	Mendeleev Communications; January 1996, Vol. 6 Issue: 6 p221-224, 4p
Abstrakt:	The dependence of the PPL-mediated optical resolution of eighteen racemic esters on the substrate's structure (the sense and magnitude of enantioselectivity, or the inertness of certain substrates) appears to be best explained by a mechanistic model involving a W-shaped active conformation of the substrate laying in a diastereodiscriminating plane.
Databáze:	Supplemental Index
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