Green Polymer Chemistry: Microwave-Assisted Single-Step Synthesis of Various (Meth)acrylamides and Poly(meth)acrylamides Directly from (Meth)acrylic Acid and Amines

Autor: Goretzki, Christian, Krlej, Andrea, Steffens, Christopher, Ritter, Helmut
Zdroj: Macromolecular Rapid Communications; February 2004, Vol. 25 Issue: 3 p513-516, 4p
Abstrakt: Summary: Various (meth)acrylamides were synthesized in good yields directly from (meth)acrylic acid and an amine using microwave irradiation in a solvent-free environment. Under the applied conditions the (meth)acrylic function is preserved. Furthermore, the addition of an initiator like 2,2'-azoisobutyronitrile (AIBN) to the starting mixture leads directly to poly(meth)acrylamides in a single step.
General reaction scheme for the formation of poly(meth)acrylamides from the microwave-assisted reaction of (meth)acrylic acid and various amines.
Databáze: Supplemental Index