| Autor: |
Paradiso, Veronica, Della Monica, Francesco, Lamparelli, David Hermann, D'Aniello, Sara, Rieger, Bernhard, Capacchione, Carmine |
| Zdroj: |
Catalysis Science & Technology; 2021, Vol. 11 Issue: 14 p4702-4707, 6p |
| Abstrakt: |
A dinuclear iron-based catalytic system, bearing a new alkyl-bridged bis-[OSSO]-type ligand, for the coupling of CO2with epoxides is reported. A turnover frequency up to 1680 h−1was recorded for propylene carbonate formation. A bimetallic cooperative reaction mechanism is proposed on the basis of kinetic analyses. These results give insights into the development of more efficient catalysts. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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