Stabilization of highly reactive cyclic polyolefins by coordination to iron carbonyls: cis-cyclononatetraene-iron tricarbonyl

Autor: Deganello, G., Maltz, H., Kozarich, J.
Zdroj: Journal of Organometallic Chemistry; November 1973, Vol. 60 Issue: 2 p323-333, 11p
Abstrakt: Reaction of cis-bicyclo[6.1.0]nona-2,4,6-triene (C9H10) (I) with Fe2(CO)9, at room temperature, yields a number of complexes (IV)–(IX). One of theśe, (IX), is the Fe2(CO)6derivative of the starting polyolefin (I), whereas the others are Fe(CO)3or Fe(CO)4complexes of isomeric C9H10polyolefins.
Databáze: Supplemental Index