Direct carbothermic reduction of ilmenite concentrates by adding high dosage of Na2CO3in microwave field

Autor: YU, Zhi-gang, XIAO, Jing-wu, LENG, Hai-yan, CHOU, Kuo-chih
Zdroj: Transactions of Nonferrous Metals Society of China; June 2021, Vol. 31 Issue: 6 p1818-1827, 10p
Abstrakt: A clean and efficient route for the utilization of ilmenite concentrates was proposed by direct carbothermic reduction in microwave field. High dosage of Na2CO3, which can be recycled, was added to accelerate the reduction reaction of ilmenite concentrates. After microwave heating in the temperature range of 1073−1123 K for 20 min, the main products were Na2TiO3and metallic Fe with the metallization ratios being as high as 92.67%−93.21%. The reduction products were processed by water leaching, ball-milling in CO2atmosphere and magnetic separation in turn. The final products after magnetic separation were Fe-rich materials and Ti-rich materials (90.04 wt.% TiO2), which can be used to produce iron and TiCl4or TiO2. The optimized heating temperature was 1123 K in terms of metallization ratios, magnetic separation and caking property of the reduction products. Besides, the reduction mechanism of ilmenite concentrates with the addition of Na2CO3in microwave field was also proposed.
Databáze: Supplemental Index