Redox Intermediates of Desulfovibrio gigas[NiFe] Hydrogenase Generated Under Hydrogen

Autor: Teixeira, M, Moura, I, Xavier, A V, Moura, J J, LeGall, J, DerVartanian, D V, Peck, H D, Huynh, B H
Zdroj: Journal of Biological Chemistry; October 1989, Vol. 264 Issue: 28 p16435-16450, 16p
Abstrakt: The hydrogenase (EC 1.2.2.1) of Desulfovibrio gigasis a complex enzyme containing one nickel center, one [3Fe-4S] and two [4Fe-4S] clusters. Redox intermediates of this enzyme were generated under hydrogen (the natural substrate) using a redox-titration technique and were studied by EPR and Mössbauer spectroscopy.
Databáze: Supplemental Index