| Autor: |
Urbansky, M., Davis, C. E., Surjan, J. D., Coates, R. M. |
| Zdroj: |
Organic Letters; January 2004, Vol. 6 Issue: 1 p135-138, 4p |
| Abstrakt: |
Two key intermediates of the newly discovered mevalonate-independent pathway for isoprenoid biosynthesis were prepared. Optically pure 2-C-methyl-d-erythritol 4-phosphate and 2,4-cyclodiphosphate were chemically synthesized from d-arabitol using a convenient benzylidene and tert-butyldimethylsilyl protection of polyhydroxylated intermediates. The new scheme offers a straightforward route to analogues and labeled forms. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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