| Autor: |
Godin, Paul J., Ramirez, Ramses M., Campbell, Charissa L., Wizenberg, Tyler, Nguyen, Tue Giang, Strong, Kimberly, Moores, John E. |
| Zdroj: |
Journal of Geophysical Research - Planets; December 2020, Vol. 125 Issue: 12 |
| Abstrakt: |
Experimental measurements of collision‐induced absorption (CIA) cross sections for CO2‐H2and CO2‐CH4complexes were performed using Fourier transform spectroscopy over a spectral range of 150–475 cm−1and a temperature range of 200–300 K. These experimentally derived CIA cross sections agree with the spectral range of the calculation by Wordsworth et al. (2017) however, the amplitude is half of what was predicted. Furthermore, the CIA cross sections reported here agree with those measured by Turbet et al. (2019, 2019). Additionally, radiative transfer calculations of the early Mars atmosphere were performed, and showed that CO2‐CH4CIA would require surface pressure greater than 3 bar for a 10% methane atmosphere to achieve 273 K at the surface. For CO2‐H2, liquid water is possible with 5% hydrogen and less than 2 bar of surface pressure. New temperature‐dependent infrared absorption properties of CO2‐H2and CO2‐CH4gas mixtures were experimentally tested against a theoretical prediction. Ultimately, we find that the strength of the absorption was half of what was predicted. Absorption between CO2‐H2and CO2‐CH4was proposed as a way to increase the greenhouse gas effect on ancient Mars, so that Mars would be warm enough to have liquid water on the surface. Ancient Mars climate was simulated using the new gas mixture absorption properties. Since the experimental absorption was weaker than predicted, we find that CO2‐CH4is insufficient in warming ancient Mars, but CO2‐H2remains a possibility. First experimental measurements of CO2‐H2and CO2‐CH4CIA cross sections at multiple temperaturesRadiative transfer calculations of the early Mars atmosphere were performed using the newly acquired CIA cross sectionsSurface temperatures above 273 K can be reached if surface pressures exceed 3 bar for 10% CH4or 2 bar for a 5% H2atmosphere First experimental measurements of CO2‐H2and CO2‐CH4CIA cross sections at multiple temperatures Radiative transfer calculations of the early Mars atmosphere were performed using the newly acquired CIA cross sections Surface temperatures above 273 K can be reached if surface pressures exceed 3 bar for 10% CH4or 2 bar for a 5% H2atmosphere |
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