Catalytic, Asymmetric Synthesis of Cyanohydrin Ethyl Carbonates

Autor:	Belokon', Y. N., Blacker, A. J., Clutterbuck, L. A., North, M.
Zdroj:	Organic Letters; November 2003, Vol. 5 Issue: 23 p4505-4507, 3p
Abstrakt:	The bimetallic titanium complex [(salen)TiO]2, where salen is the ligand derived from (R,R)-cyclohexanediamine and 3,5-di-tert-butyl-salicylaldehyde, has been shown to catalyze the asymmetric addition of ethyl cyanoformate to aldehydes leading to cyanohydrin carbonates with high enantiomeric excesses.
Databáze:	Supplemental Index
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