Characteristics of Electron Transport Study of Composited Graphene-Zinc Oxide Thin Film Photoanode for Dye-Sensitized Solar Cells

Autor: Samsi, Noor Syafiqah, Affendi, N.A.S., Yaakob, M.K., Taib, M.F.M., Lepit, A., Hassan, Oskar Hasdinor, Yahya, M.Z.A., Ali, A.M.M.
Zdroj: Diffusion and Defect Data Part B: Solid State Phenomena; July 2020, Vol. 307 Issue: 1 p185-191, 7p
Abstrakt: Graphene-Zinc Oxide (Gr-ZnO) nanocomposites films were successfully synthesized via facile electrodeposition method in an aqueous solution under Gr concentration conditions. Gr, as a highly conductive carbon, acts as an anchor for ZnO nanosheets and plays a substantial role in controlling the degree of dispersion of ZnO nanosheets onto indium-doped tin oxide (ITO) substrate to form Gr-ZnO nanocomposite. Atomic force microscopy (AFM) and field-emission scanning electron microscopy (FESEM) analysis of Gr-ZnO nanocomposite samples confirmed that the presence of ZnO nanosheets with a high degree of dispersity and crystallinity which is well linked to the thin layer of Gr nanoparticle on ITO substrate. The surface roughness of the films found increased to ~270 nm on Gr-ZnO as compared to Gr ~44 nm and ZnO ~3 nm. Further, the x-ray diffraction spectroscopy (XRD) analysis showed the result is in good agreement with Raman spectroscopy study. The cyclic voltammetry (CV) of Gr-ZnO nanocomposite revealed that the effect of electron-hole recombination process was increased and the presence of Gr in ZnO photoanode provides the fastest redox reaction and hence offers the fastest electron transfer in photoanode.
Databáze: Supplemental Index