Oxosulfido Complexes of Platinum — (Ph3P)2Pt(S2O) and (Ph3P)4Pt2(μ-S)(μ-SO) — Their Formation and Properties

Autor: Ishii, Akihiko, Murata, Masami, Oshida, Hideaki, Matsumoto, Kimiyo, Nakayama, Juzo
Zdroj: European Journal of Inorganic Chemistry; October 2003, Vol. 2003 Issue: 20 p3716-3721, 6p
Abstrakt: The platinum S2O complex [(Ph3P)2Pt(S2O)] (10) was obtained by S2O transfer reactions from tetrathiolane 2-oxide (8), tetrathiolane 2,3-dioxide (5), and pentathiane 3-oxide (6) to [(C2H4)Pt(PPh3)2] (4). The S2O complex 10 further reacts with 4 to give a novel binuclear platinum complex 16, which is found to be a source of several platinum SnOm complexes. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Databáze: Supplemental Index