(Cyclopentadienylamine)scandium(2,3-dimethyl-1,3-butadiene):  A 1,3-Diene Complex of Scandium with Sc(I)- and Sc(III)-like Reactivity

Autor:	Beetstra, D. J., Meetsma, A., Hessen, B., Teuben, J. H.
Zdroj:	Organometallics; October 2003, Vol. 22 Issue: 22 p4372-4374, 3p
Abstrakt:	The scandium 2,3-dimethyl-1,3-butadiene complex [η5,η1-C5H4(CH2)2NMe2]Sc(C6H10) (2) reacts with PhCN via initial nitrile insertion into the Sc−diene bond to give a dimeric μ2-imido species, but with a 2,2‘-bipyridine via the elimination of the free diene. The latter shows that 2 can be used to generate the reactive fragment [η5,η1-C5H4(CH2)2NMe2]ScI.
Databáze:	Supplemental Index
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