Phase transition in C2O4DND4, ${\bf 1}/{\bf 2}$D2O : a coherent inelastic neutron scattering study

Autor: Krauzman, M., Debeau, M., Pick, R. M., Quilichini, M., Launois, P., Moussa, F., Krauzman, M., Debeau, M., Pick, R. M., Quilichini, M., Launois, P., Moussa, F.
Zdroj: Journal de Physique I; March 1992, Vol. 2 Issue: 3 p329-351, 23p
Abstrakt: The low frequency dynamics related to the second order transition which takes place in ammonium deuterated oxalate has been investigated by coherent inelastic neutron scattering. This transition leads to a ferroelastic phase at zero presure and to an incommensurate phase at 5kbar. At both pressures, our experiments show that the coupling between a reorientation motion of one family of ND+4ions and the TA phonons propagating along c*and polarized along adrives the transition, the ND4+being coupled through a pressure dependent ANNNI model. Weak changes in the parameters explain the changes with pressure of the static and dynamical properties of the transition.
Databáze: Supplemental Index