The Temperature Dependent Shear-Strain of the (NbSe$\bf_4$)$\bf_{10}$I$\bf_3$Compound, a Quasi-One-Dimensional Charge Density Wave System, below the Peierls Transition

Autor: Vučić, Z., Gladić, J., Haas, C., De Boer, J. L., Vučić, Z., Gladić, J., Haas, C., De Boer, J. L.
Zdroj: Journal de Physique I; February 1996, Vol. 6 Issue: 2 p265-275, 11p
Abstrakt: An X-ray study of the quasi-one-dimensional charge density wave (CDW) system (NbS4)10I3as a function of temperature from room temperature down to 130 K has been performed by taking oscillation and zeroth level Weissenberg photographs. A reversible transformation of the room temperature tetragonal lattice into four symmetrically-related monoclinic domains has been observed at the Peierls transition temperature, TP≈285 K, with a continuous change of the monoclinic angle from 90° to 92.1° at 130 K. The monoclinic deformation of the tetragonal lattice, i.e. the shear-strain along the chain axis seems to be an elastic response to the long wavelength transverse modulation of the 3D-CDW order which can be qualitatively explained by taking into account the Coulomb interaction between CDWs on neighbouring chains up to the next-nearest-neighbours.
Databáze: Supplemental Index