Carbene Adduct as Overcharge Protecting Agent in Lithium Ion Batteries

Autor: Dippel, Christian, Schmitz, Rene, Muller, Romek, Bottcher, Tobias, Kunze, Miriam, Lex, Alexandra, Roschenthaler, Volker, Passerini, Stefano, Winter, Martin
Zdroj: Journal of the Electrochemical Society; January 2012, Vol. 159 Issue: 10 pA1587-A1590, 4p
Abstrakt: We investigated an N-heterocyclic-carbene-PF5 adduct (NHC-PF5) as additive for overcharge protection of a lithium nickel cobalt oxide (NCM) cathode by linear potential sweep methods and constant current experiments. The NHC-PF5 additive was oxidized at a potential of 4.57 V vs. Li/Li+ thus protecting the NCM cathode from overcharge. No detrimental influence of the additive on the cycling behavior of NCM/graphite full cells was observed.
Databáze: Supplemental Index