Studies on Complexing Properties of 2,4,6-Trifluorophenylboronic Acid Pinacol Ester in PEODME Based Polymer Electrolyte

Autor: Kryczka, Jolanta, Drzewiecki, Stanislaw, Szczypinska, Joanna, Zukowska, Zofia, Adamczyk, Agnieszka, Syzdek, Jaroslaw S., Marcinek, Marek, Sporzynski, Andrzej, Wieczorek, Wladyslaw
Zdroj: ECS Transactions; April 2010, Vol. 25 Issue: 36 p61-71, 11p
Abstrakt: In this paper we present our systematic studies on the application of new organoboron compound as anion complexing additive in poly(ethylene oxide) dimethyl ether PEGDME-lithium salt. The anion trapping ability of this compounds is discussed regarding the type of various compounds, both triarylboranes as well as arylboronic esters. A possible mechanism of interactions is verified by the impedance spectroscopy, differential scanning calorimetry and vibrational spectroscopy methods.
Databáze: Supplemental Index