Stabilized Lithium, Manganese AB2O4 Spinel for Rechargeable Lithium Electrochemical Systems through A and B Site Doping

Autor: Howarth, Yakira J, Atwater, Terrill B
Zdroj: ECS Transactions; October 2017, Vol. 80 Issue: 10 p317-324, 8p
Abstrakt: Lithium manganese oxide doped with potassium and cobalt produces a promising cathode material for rechargeable lithium-ion cells. Modifying the A site and B site of the spinel structure works to limit cathodic capacity fading by enhancing the robustness of the material. LixKyMn2-zCozO4 was synthesized as the active ingredient for the cathode with x=1, y=0.1, and both z=0.1 and 0.2, and was tested against metallic lithium to evaluate performance. Through high-rate discharge, pulse cycling, and deep discharge tests, the electrochemistry of the cathode exhibited excellent reversibility and overall performance stability. LiK0.1Mn2-zCozO4 proved to be a capable abuse tolerant option for use in rechargeable battery applications.
Databáze: Supplemental Index