Copper-free, recoverable dendritic Pd catalysts for the Sonogashira reaction

Autor: Heuzé, Karine, Méry, Denise, Gauss, Dominik, Astruc, Didier
Zdroj: Chemical Communications; 2003, Vol. 2003 Issue: 18 p2274-2275, 2p
Abstrakt: Three generations of bidentate phosphinated Pd(ii) dendrimers are efficient catalysts in the absence of copper co-catalyst for the Sonogashira reaction and are, with two cyclohexyl substituents on the phosphorus atoms, recovered by precipitation and re-used.
Databáze: Supplemental Index