The stereochemical course of sulphuryl transfer catalysed by arylsulphatase II from Aspergillus oryzae

Autor: Chai, C L L, Loughlin, W A, Lowe, G
Zdroj: Biochemical Journal; November 1992, Vol. 287 Issue: 3 p805-812, 8p
Abstrakt: Phenyl [(R)-16O,17O,18O]sulphate was synthesized and used to study the stereochemical course of sulphuryl transfer to p-cresol catalysed by arylsulphatase II from Aspergillus oryzae. The reaction was shown to proceed with retention of configuration at the sulphur atom, providing evidence for the involvement of a sulpho-enzyme intermediate on the reaction pathway.
Databáze: Supplemental Index