The preparation and properties of bromoacetylphosphonic acid

Autor: Sparkes, M J, Dixon, H B F
Zdroj: Biochemical Journal; May 1991, Vol. 275 Issue: 3 p772-773, 2p
Abstrakt: Bromoacetylphosphonic acid, Br-CH2-CO-PO3H2, was made by brominating dimethyl acetylphosphonate and de-esterifying with HBr. It proves to be a powerful alkylating agent, reacting rapidly with GSH, with a rate constant of about 6M(-1).s(-1) at pH6.
Databáze: Supplemental Index