| Abstrakt: |
Abstract: A series of poly(ionic liquid)s (PILs) incorporating 1,2,3-triazolium and imide units are synthesized in three steps by AA?+?BB polyaddition between a,?-diazido tetraethylene glycol and three aromatic bis-imide dipropargyl monomers using copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) followed by N-alkylation of the resulting poly(1,2,3-triazole imide)s with iodomethane and subsequent anion exchange with lithium bis(trifluoromethylsulfonyl)imide. Structure/properties correlations of poly(1,2,3-triazole imide)s and corresponding poly(1,2,3-triazolium imide)s are discussed based on NMR spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), size exclusion chromatography (SEC) and solubility measurements. Graphic Abstract: ![]() |
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