Rotational Spectroscopy of Mixtures of Trimethylamine and Fluorine: Identification of the Ion Pair [(CH3)3NF]+…? F-in the Gas Phase

Autor: Bloemink, Hannelore I., Cooke, Stephen A., Legon, A. C., Holloway, John H.
Zdroj: Angewandte Chemie. International Edition; July 1997, Vol. 36 Issue: 12 p1340-1342, 3p
Abstrakt: Abstraction of a F+ion from F2leading to formation of the ion pair [(CH3)3]NF+…? F-occurs when trimethylamine and F2are mixed in the gas phase under conditions that preclude production of F atoms. The presence of this ion pair in (CH3)3N/F2mixtures emerging from a fast-mixing nozzle has been unambiguously established from several of its properties determined by rotational spectroscopy.
Databáze: Supplemental Index