Autor: |
Bloemink, Hannelore I., Cooke, Stephen A., Legon, A. C., Holloway, John H. |
Zdroj: |
Angewandte Chemie. International Edition; July 1997, Vol. 36 Issue: 12 p1340-1342, 3p |
Abstrakt: |
Abstraction of a F+ion from F2leading to formation of the ion pair [(CH3)3]NF+…? F-occurs when trimethylamine and F2are mixed in the gas phase under conditions that preclude production of F atoms. The presence of this ion pair in (CH3)3N/F2mixtures emerging from a fast-mixing nozzle has been unambiguously established from several of its properties determined by rotational spectroscopy. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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