| Autor: |
Ponte Goncalves, A.M., Burgner, R.P. |
| Zdroj: |
Chemical Physics Letters; March 1977, Vol. 46 Issue: 3 p488-492, 5p |
| Abstrakt: |
The radiationless decay rate constants of the zero field spin sublevels of the lowest triplet state of meso-tetra (m-fluoro-phenyl)porphin free base are reported. The values for the base deuterated at the N—H positions are also given. Deuteration affects the fast in-plane spin state more than the slow in-plane spin state, (khα/kdα) : (khβ/kdβ= 0.75. The role of out-of-plane N—H vibrations as promoting modes is discussed in terms of the theory of Metz and co-workers. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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