| Autor: |
Du, Yi-Dan, Xu, Zhen-Jiang, Zhou, Cong-Ying, Che, Chi-Ming |
| Zdroj: |
Organic Letters; January 2019, Vol. 21 Issue: 4 p895-899, 5p |
| Abstrakt: |
[FeIII(TF4DMAP)Cl] can efficiently catalyze intermolecular sp3C–H amination using aryl azides and intramolecular sp3C–H amination of alkyl azides in moderate-to-high product yields. At catalyst loading down to 1 mol %, the reactions display high chemo- and regioselectivity with broad substrate scope and are effective for late-stage functionalization of complex natural/bioactive molecules. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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