| Autor: |
Ma, Zi Jun, Li, Qun Yan, Ma, Kai Rui, Sun, Shi Bing, Wei, Qi, Cui, Su Ping |
| Zdroj: |
Diffusion and Defect Data Part B: Solid State Phenomena; August 2018, Vol. 281 Issue: 1 p842-847, 6p |
| Abstrakt: |
The hollow mesoporous SiO2/dense SiO2/Fe3O4 composite particles with different pore sizes were prepared by a multistep coating technique. TEOS as a silicon source, and P123 were combinated with co-surfactant CTAB as template to coat mesoporous on the dense SiO2/Fe3O4 composite particles. The influence of the pore diameter in the composite particles on the laccase immobilization amount in the composite particles and the catalytic efficiency of 2,4-dichlorophenol on hollow composite particles were researched in detail. When the pore diameter of the hollow composite particles was 4.30 nm, the laccase immobilization amount reached the maximum (234 mg/g). The pH was within 3 ~ 8 range, and the activity of immobilized laccase was obviously higher than that of free laccase molecule. And the relative activity of immobilized lactase was highest when pH was 4. When the temperature was within 303K ~ 353K, the immobilized laccase had higher relative activity than free laccase and the activity of immobilized laccase still remained 28%. The removal rate of 2,4-dichlorophenol of immobilized laccase in the composite particles was about 80%. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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