| Autor: |
Nivlet, Alex, Guen, Valérie Le, Dechoux, Luc, Gall, Thierry Le, Mioskowski, Charles |
| Zdroj: |
Tetrahedron Letters; January 1998, Vol. 39 Issue: 15 p2115-2118, 4p |
| Abstrakt: |
The regioselectivity of the reductive opening of cyclopropylogous α-hydroxy carbonyl compounds using SmI 2in THF or THF-HMPA was studied and shown to depend strongly on the substrate. In some cases, a tandem cyclopropyl opening-deoxygenation reaction afforded the corresponding γ-keto alkenes in one step. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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