| Autor: |
Yoon, Juyoung, Ohler, Norman E., Vance, David H., Aumiller, Wade D., Czarnik, Anthony W. |
| Zdroj: |
Tetrahedron Letters; January 1997, Vol. 38 Issue: 22 p3845-3848, 4p |
| Abstrakt: |
Geometric immobilization of polyamine ligands is expected to change their binding properties toward practical ion discrimination. Chemosensor 5senses only two transition metal ions in water- Hg(II) (K d≤1 μM) and Cu(II) (K d56 μM)- which can be compared with bindings of a non-immobilized reference compound (9-(trpnmethyl)-anthracene; 3) with Hg(II) (K d14 μM) and Cu(II) (K d39 μM). A related bridged cyclen derivative ( 7) showed no effect on fluorescence by any metal ion examined. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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