Autor: |
Yamanoi, Shigeo, Imai, Takahiro, Matsumoto, Takashi, Suzuki*, Keisuke |
Zdroj: |
Tetrahedron Letters; January 1997, Vol. 38 Issue: 17 p3031-3034, 4p |
Abstrakt: |
A regio- and stereocontrolled method for the allylmetallation of 1-alkynes is described. The allylzirconium species, generated by hydrozirconation of allenes, undergo regioselective addition to 1-alkynes in the presence of organoaluminum reagents among which methylaluminoxane (MAO) is particularly effective. © 1997 Elsevier Science Ltd. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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