Palladium (0) catalysed rearrangements of allylic sulfoximines to allyl sulfinimidic acid esters and optically active N-Cbz protected γ-amino-enones

Autor: Pyne, Stephen G., David, Dorothy M., Dong, Zemin
Zdroj: Tetrahedron Letters; January 1998, Vol. 39 Issue: 46 p8499-8502, 4p
Abstrakt: N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimidic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected γ-amino-enones.
Databáze: Supplemental Index