Catalytic aminohydroxylation using adenine-derivatives as the nitrogen source

Autor: Dress, K.Ruprecht, Gooßen, Lukas J., Liu, Hong, Jerina, Donald M., Sharpless, K.Barry
Zdroj: Tetrahedron Letters; January 1998, Vol. 39 Issue: 42 p7669-7672, 4p
Abstrakt: The -chloro-N-sodio salts of adenine derivatives are suitable nitrogen sources for the osmium catalyzed aminohydroxylation of olefins, achieving suprafacial, vicinal addition of adenine and a hydroxyl group. The scope of this transformation was examined using adenine and adenosine-derivatives in conjunction with three different olefins.
Databáze: Supplemental Index